柔性电极
一种制备超薄金属薄膜作为耐刮擦柔性透明电极的新方法
Authors: Yuan Liu, Chuan-Fei Guo, Siya Huang, Tianyi Sun, Yumei Wang, Zhifeng Ren
Volume 1, Issue 1, Pages 52-59
左侧为传统方法,右侧为多层沉积新方法且表面形成了氧化膜
Metals are favorable candidates for flexible transparent electrodes because they have high electrical conductivity and good ductility.
金属具有高导电性和韧性,是做柔性透明电极的理想材料。
Theoretically, ultrathin metal films can present low sheet resistance and high transmittance simultaneously.
理论上,超薄金属薄膜可以同时呈现低薄层电阻和高透射率。
However, due to Ostwald ripening many metal films (e.g., Ag) tend to form in island growth mode, leading to isolated metal islands and non-conducting feature until the films become relatively opaque.
然而,由于Ostwald熟化作用,许多金属膜(例如Ag)倾向于以岛状生长,形成孤立的金属岛,具有非导电特征,直至形成较不透明的膜。
Here we present a new vacuum deposition method that can effectively suppress the Ostwald ripening in metal films, which become conducting at a thickness much smaller than the percolation threshold.
我们提出一种新的真空沉积方法可以有效抑制金属膜的Ostwald熟化作用,使得制得的金属薄膜厚度远小于逾渗阈值。
The conducting and transparent metal films are smooth and scratch-resistant, and are stretchable by forming distributed ruptures upon stretching.
这个导电且透明的金属薄膜平滑且耐刮擦。受拉时通过形成间断的破裂而具有可拉伸性。
This work presents a new and versatile strategy to fabricate scratch-resistant flexible transparent electrodes.
本工作提出了一种制备耐刮擦柔性透明电极的巧妙新方法。
文中部分图片:
一次和多次沉积的微观形貌和物相分析
Fig. 3. (a) TEM image of Ag film deposited in one time (8 nm × 1 layer). (b) TEM image, (c) high resolution TEM image, and (d) electron diffraction patterns of Ag film deposited in four times (2 nm × 4 layers).
薄层电阻和光透射率
Fig. 4. (a–c) Optical transmittance spectra and sheet resistance of multi-layer Ag films with different thickness. (d) Simulation of optical transmittance spectra of Ag film (D = 10 nm) with PEFOT:PSS coating (D = 40–60 nm) on 1-mm-thick glass substrate.
多层银薄膜和Al掺杂银薄膜的薄层电阻对比
Fig. 5. Comparison of performances between our multi-layer Ag films and Al-doped Ag films [21].
拉伸性能
Fig. 6. Rs/R0 and Rr/R0 (a) as a function of tensile strain, and (b) as a function of stretching cycles after releasing from 30% strain. The Ag film is 2.2 nm × 4 layers thick deposited on PDMS substrate with 30% pre-strain.
多层沉积制备的银薄膜受拉后的微观形貌
Fig. 7. SEM images of distributed ruptures in Ag film on a tape under (a) small strain (b) increased strain. The arrows indicate the strain directions.
来自休斯顿大学的Professor Ren带领的团队所做的工作可谓是创意满满、有理有据、条理清晰,赞。让我们来认识下他吧!
Yuan Liu is currently a graduate student pursuing her Ph.D. degree in the Department of Physics at the University of Houston, USA. She obtained her B.S. Degree in Physics from Nanjing University, China. Her current research is mainly on nanomaterials and nano-fabrication for applications in flexible transparent conductors in addition to thermoelectrics.
Dr. Chuanfei Guo is a research associate fellow in the Department of Physics and TcSUH at the University of Houston, USA. He earned a Ph.D. degree from the National Center for Nanoscience & Technology of China, Chinese Academy of Sciences in 2011, a B.S. degree from the Huazhong University of Science & Technology, China, in 2006. He joined Prof. Zhifeng Ren's group since 2011. His research focuses on nanomaterials, nano-/micro-fabrication, flexible electronics, photovoltaics, and thermoelectrics.
Dr. Zhifeng Ren is an M.D. Anderson Chair Professor in Physics and Texas Center for Superconductivity at University of Houston. He obtained his Ph.D. from Institute of Physics, Chinese Academy of Sciences, master from Huazhong University of Science and Technology, and bachelor from Sichuan Institute of Technology. He was a postdoc and research professor at SUNY Buffalo and professor at Boston College. He specializes in thermoelectric materials and devices, flexible transparent conductors, photovoltaics, carbon nanotubes, superconductors, etc. He is a fellow of the APS, AAAS and NAI. He is recipient of the R&D 100 award and O׳Donnell award of TAMEST.
最后再向大家介绍一下我们闪亮亮的JMAT期刊。它的全称是Journal of Materiomics,是由中国硅酸盐学会和Elsevier合作出版的英文期刊,现已在ScienceDirect上发布了第五卷第1期(2019年),点击文末“阅读全文“可自由获取所有论文全文。
Journal of Materiomics 为同行评议期刊,被web of science和scopus收录,最新出炉的2018年cite score为8.02,从投稿到在线出版一般只需60天,并且对作者免收发表费!投稿说明详见https://www.journals.elsevier.com/journal-of-materiomics/, 期望大家不吝赐稿。