Two novel 3D pure inorganic compounds based on [CrDy(μ-O)(μ-OH)] cluster units and sulfate anions are presented. Both complexes exhibit single-molecule-magnet (SMM)-like behavior. Permutation of the magnetic moment direction among SMM-like cluster units has a significant effect on the performance of molecular nanomagnets, and directional consistency shows obvious advantages.
Caiming Liu Deqing Zhang Xiang Hao 朱道本
Inorganic Chemistry
2018