Improved cycling stability of silicon thin film electrodes through patterning for high energy density lithium batteries

X. Xiao;平 刘;M. W. Verbrugge;H. Haftbaradaran;华健 高

General Motors;China Association for Science and Technology;Brown University

发表时间:2011-2-1

期 刊:Journal of Power Sources

语 言:English

U R L: http://www.scopus.com/inward/record.url?scp=78049405664&partnerID=8YFLogxK

摘要

The mechanical degradation of electrodes caused by lithiation and delithiation is one of the main factors responsible for the short cycle life of lithium-based batteries employing high capacity electrodes. In this report, we introduced a simple patterning approach to improve the cycling stability of silicon electrode, which is considered as the next generation negative electrode due to its high Coulombic capacity and low cost, but is limited by the mechanical degradation associated with large volume variations during cycling. The pattern design is based on the observation of a critical size for the crack gap in continuous films. An improvement in cycle life was noted when the pattern size was below the critical (7-10 μm) size, in which case the Si electrode patches adhered well to the Cu substrate after many cycles. By taking the plastic deformation in both Si thin film and substrate into consideration, the calculated crack spacing is consistent with experimental observations. Theoretical considerations gave a feasible explanation for the failure of Si pattern above the critical size. These results suggest a new approach to extend the cycle life of Si-based electrode materials using size to control and relax the stress due to lithiation and delithiation.

关键词

Crack
Lithium ion battery
Mechanical degradation
Negative electrode
Patterning
Silicon

相关科学

化学
物理和理论化学
能源学
能源工程和技术
可再生能源、可持续性和环境
工程
电子电气工程

文献指纹

物理与天文学

lithium batteries

flux density

cycles

electrodes

silicon

thin films

cracks

degradation

electrode materials

electric batteries

lithium

plastic deformation

spacing

化合物

Lithium batteries

Silicon

Thin films

Electrodes

Life cycle

Substrates

Degradation

Cracks

Lithium

Plastic deformation

Costs

工程与材料科学

Lithium batteries

Thin films

Silicon

Electrodes

Life cycle

Substrates

Degradation

Cracks

Lithium

Plastic deformation

Costs

被引量

期刊度量

Scopus度量

年份 CiteScore SJR SNIP
1996
1997
1998
1999 0.814 0.991
2000 1.091 0.946
2001 1.146 1.482
2002 1.939 1.377
2003 1.66 1.593
2004 1.85 1.769
2005 1.656 1.903
2006 1.802 2.268
2007 1.587 1.512
2008 1.96 1.715
2009 2.105 1.778
2010 2.294 1.964
2011 7.5 2.227 2.167
2012 8.3 2.282 2.007
2013 9.1 1.975 2.112
2014 9.3 1.964 2.086
2015 9.9 1.9 1.723
2016 11.6 1.944 1.544
2017 13.6 2.202 1.562
2018 13.8 1.947 1.484
2019 14.4 2.111 1.638
2020 12.9

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