Phytomining, although predominantly in its early stages on the broader scientific scope of investigation, has garnered interest in metals such as Ni, Au, or rare earth elements (REE). However, Zn pollution from mine wastes, smelters, coal ash and other anthropogenic sources has become an environmental problem. Phytoremediation by hyperaccumulating plants is one of the proposed solutions to mitigate the pollution. Therefore, a need to utilize or dispose Zn hyperaccumulating plants occurred. Since studies of certain hyperaccumulating plant species have been previously conducted in order to extract metal products, similar hydrometallurgical and pyrometallurgical techniques were tried with Zn. The hydrometallurgical route was more focused on producing crude eco catalysts for organic chemistry or separating metal hydroxides by cementation. This was achieved with acid leaching of the ash which was obtained by calcinating the aboveground plant biomass. On the other hand, the pyrometallurgical route was more focused on safe and eco-friendly disposal of combustion products such as ash or biochar, while achieving zero toxic gaseous emissions from biomass pyrolysis. Regardless of the approach further research is needed to investigate the stabilization of metals that remain in the solid fraction during combustion and lowering the metal content in produced gases. So far, none of these technologies have been brought to a semi industrial scale and there is the potential of linking those two approaches together.
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