Rongrong Hu;Erik Lager;Angélica Aguilar-Aguilar;Jianzhao Liu;Jacky W.Y. Lam;Herman H.Y. Sung;Ian D. Williams;Yongchun Zhong;Kam Sing Wong;Eduardo Peña-Cabrera;本忠 唐
Hong Kong University of Science and Technology;Universidad de Guanajuato;China Association for Science and Technology
发表时间:2009-9-10
期 刊:Journal of Physical Chemistry C
语 言:English
U R L: http://www.scopus.com/inward/record.url?scp=70349113808&partnerID=8YFLogxK
Boron dipyrromethene (BODIPY) derivatives 1 and 2 consisting of donor and acceptor units with dual photoresponses to solvent polarity and luminogen aggregation are developed through taking advantage of twisted intramolecular charge transfer (TICT) and aggregation-induced emission (AIE) processes. In nonpolar solvents, the locally excited (LE) states of the BODIPY luminogens emit intense green lights. Increasing solvent polarity brings the luminogens from the LE state to the TICT state, causing a large bathochromic shift in the emission color but a dramatic decrease in the emission efficiency. The red emission is greatly boosted by aggregate formation or AIE effect: addition of large amounts of water into the solutions of 1 and 2 in the polar solvents causes the luminogens to aggregate supramolecularly and to emit efficiently. The emission can be enhanced by increasing solvent viscosity and decreasing solution temperature, indicating that the AIE effect is caused by the restriction of the intramolecular rotations in the aggregates of the luminogens.
化合物
工程与材料科学
物理与天文学
Scopus度量
年份 | CiteScore | SJR | SNIP |
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1996 | |||
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1998 | |||
1999 | |||
2000 | |||
2001 | |||
2002 | |||
2003 | |||
2004 | |||
2005 | |||
2006 | |||
2007 | |||
2008 | 1.883 | 1.033 | |
2009 | 2.158 | 1.42 | |
2010 | 2.462 | 1.365 | |
2011 | 7.6 | 2.339 | 1.473 |
2012 | 8 | 2.529 | 1.462 |
2013 | 8.3 | 2.143 | 1.434 |
2014 | 8.4 | 2.032 | 1.434 |
2015 | 7.9 | 1.886 | 1.246 |
2016 | 7.9 | 1.964 | 1.189 |
2017 | 7.9 | 2.135 | 1.136 |
2018 | 7.6 | 1.652 | 1.096 |
2019 | 7.3 | 1.477 | 1.047 |
2020 | 7.1 | 1.401 | 0.962 |
2021 | 6 |
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