Lourdes Betancourt-Mendiola;Ismael Valois-Escamilla;Teresa Arbeloa;Jorge Bañuelos;Iñigo López Arbeloa;Juan O. Flores-Rizo;Rongrong Hu;Erik Lager;César F.A. Gómez-Durán;José L. Belmonte-Vázquez;Mayra R. Martínez-González;Ismael J. Arroyo;Carlos A. Osorio-Martínez;Enrique Alvarado-Martínez;Arlette Urías-Benavides;Brenda D. Gutiérrez-Ramos;本忠 唐;Eduardo Peña-Cabrera
Universidad de Guanajuato;University of the Basque Country;Hong Kong University of Science and Technology;China Association for Science and Technology
发表时间:2015-6-5
期 刊:Journal of Organic Chemistry
语 言:English
U R L: http://www.scopus.com/inward/record.url?scp=84930623759&partnerID=8YFLogxK
Several new examples of meso-(het)arylBODIPY were prepared via the Liebeskind-Srogl (L-S) cross-coupling reaction of the Biellmann BODIPYs (1a,b) and aryl- and heteroarylboronic acids in good to excellent yield. It was shown that this reaction could be carried out under microwave heating to shorten reaction times and/or increase the yield. It was illustrated that organostannanes also participate in the L-S reaction to give the corresponding BODIPY analogues in short reaction times and also with good to excellent yields. We analyze the role of the substituent at the sensitive meso position in the photophysical signatures of these compounds. In particular, the rotational motion of the aryl ring and the electron donor ability of the anchored moieties rule the nonradiative pathways and, hence, have a deep impact in the fluorescence efficiency.
化合物
Scopus度量
年份 | CiteScore | SJR | SNIP |
---|---|---|---|
1996 | |||
1997 | |||
1998 | |||
1999 | 1.943 | 1.317 | |
2000 | 2.165 | 1.319 | |
2001 | 2.048 | 1.354 | |
2002 | 2.318 | 1.411 | |
2003 | 1.912 | 1.324 | |
2004 | 1.956 | 1.291 | |
2005 | 2.03 | 1.28 | |
2006 | 2.249 | 1.289 | |
2007 | 2.389 | 1.287 | |
2008 | 2.349 | 1.208 | |
2009 | 2.198 | 1.254 | |
2010 | 2.127 | 1.17 | |
2011 | 7.7 | 2.265 | 1.243 |
2012 | 7.9 | 2.286 | 1.228 |
2013 | 7.7 | 2.092 | 1.17 |
2014 | 8.1 | 2.007 | 1.226 |
2015 | 8.1 | 1.997 | 1.164 |
2016 | 8.3 | 2.001 | 1.049 |
2017 | 8.4 | 1.846 | 1.01 |
2018 | 8.1 | 1.607 | 0.962 |
2019 | 7.8 | 1.349 | 0.987 |
2020 | 7.2 |
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