Mesoporous TiO₂ has gained increasing interest because of its outstanding properties and promising applications in a wide range of fields. Herein, we report the facile synthesis of ordered mesoporous black TiO ₂ (OMBT) materials, which exhibit excellent photocatalytic hydrogen evolution performances. In this case, the employment of a thermally stable and high-surface-area mesoporous TiO₂ as the hydrogenation precursor is the key for fabricating the OMBT materials, which not only facilitate H ₂ gas diffusion into TiO₂ and interaction with their structures but also maintain the ordered mesoporous structures as well as inhibit the phase transformation (from anatase to rutile) and crystal growth during hydrogenation at 500°C. The resultant OMBT materials possess a relatively high surface area of ∼124 m² g^-1 and a large pore size and pore volume of ∼9.6 nm and 0.24 cm³ g ^-1, respectively. More importantly, the OMBT materials can extend the photoresponse from ultraviolet to visible and infrared light regions and exhibit a high solar-driven hydrogen production rate (136.2 μmol h ^-1), which is almost two times as high as that of pristine mesoporous TiO₂ (76.6 μmol h^-1).