Single-turn helix-coil strands stabilized by metal metal and π-π Interactions of the alkynylplatinum(II) terpyridyl moieties in meta -phenylene ethynylene foldamers

Sammual Yu Lut Leung;Anthony Yiu Yan Tam;Chi Hang Tao;Hoi Shan Chow;咏华 任

The University of Hong Kong

发表时间:2012-1-18

期 刊:Journal of the American Chemical Society

语 言:English

U R L: http://www.scopus.com/inward/record.url?scp=84855928711&partnerID=8YFLogxK

摘要

Dinuclear alkynylplatinum(II) terpyridyl complexes with oligomeric bridge consisting of five repeating meta-phenylene ethynylene (mPE) units have been found to exhibit a strong tendency to fold back onto themselves to form short helical strands through the stabilization of Pt Pt and π-π interactions. The steric bulk of the terpyridine ligands and the length of the oligomeric bridge have been found to affect the extent of the intramolecular Pt Pt interaction that governs the stabilization of the short helical strand in solution. Their folding properties via Pt Pt and π-π stacking interactions have been studied by 1H NMR, 2D ROESY NMR, electronic absorption, and emission spectroscopies.

相关科学

生物化学、遗传学和分子生物学
生物化学
化学工程
催化
胶体与表面化学
化学

文献指纹

化合物

meta-phenylene ethynylene

Nuclear magnetic resonance

Metals

Emission spectroscopy

Stabilization

Absorption spectroscopy

Ligands

医学与生命科学

meta-phenylene ethynylene

Proton Magnetic Resonance Spectroscopy

Spectrum Analysis

Metals

Ligands

工程与材料科学

Nuclear magnetic resonance

Emission spectroscopy

Stabilization

Absorption spectroscopy

Ligands

Metals

被引量

期刊度量

Scopus度量

年份 CiteScore SJR SNIP
1996
1997
1998
1999 3.438 2.106
2000 3.589 2.141
2001 3.506 2.112
2002 3.587 2.324
2003 3.421 2.223
2004 3.841 2.187
2005 4.413 2.205
2006 4.662 2.229
2007 5.202 2.134
2008 5.06 2.121
2009 4.958 2.199
2010 5.167 2.14
2011 16.1 5.478 2.326
2012 17.4 6.211 2.373
2013 19.3 5.993 2.446
2014 20.9 6.294 2.568
2015 22.4 6.775 2.602
2016 23.5 7.492 2.608
2017 24 8.127 2.634
2018 24.4 7.468 2.652
2019 24.8 6.976 2.682
2020 25
2021

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