Solvent-induced aggregation through metal···metal/π···π interactions

咏华 任;Keith Man Chung Wong;Nianyong Zhu

China Association for Science and Technology;The University of Hong Kong

发表时间:2002-6-12

期 刊:Journal of the American Chemical Society

语 言:English

U R L: http://www.scopus.com/inward/record.url?scp=0037067013&partnerID=8YFLogxK

摘要

A dramatic color change and tremendous emission enhancement have been "switched on" upon increasing diethyl ether ratio in acetonitrile or acetone solution of [Pt(tpy)(C≡C-C≡CH)]OTf, attributed to the formation of Pt⋯Pt and π-π interactions. Two crystal forms (dark-green and red) of [Pt(tpy)(C≡C-C≡CH)]OTf, together with [Pt(tBu3-tpy)(C≡C-C≡CH)]OTf, show different crystal-packing modes as revealed by X-ray crystallography.

相关科学

生物化学、遗传学和分子生物学
生物化学
化学工程
催化
胶体与表面化学
化学

文献指纹

医学与生命科学

X Ray Crystallography

acetonitrile

Acetone

Ether

Color

化合物

Crystals

Agglomeration

X ray crystallography

acetonitrile

Acetone

Ether

Color

工程与材料科学

Crystals

Agglomeration

X ray crystallography

Acetonitrile

Acetone

Ethers

Color

被引量

期刊度量

Scopus度量

年份 CiteScore SJR SNIP
1996
1997
1998
1999 3.438 2.116
2000 3.589 2.149
2001 3.506 2.118
2002 3.587 2.326
2003 3.421 2.236
2004 3.841 2.199
2005 4.413 2.205
2006 4.662 2.229
2007 5.202 2.137
2008 5.06 2.114
2009 4.958 2.205
2010 5.167 2.14
2011 16.1 5.478 2.326
2012 17.4 6.211 2.373
2013 19.3 5.993 2.446
2014 20.9 6.294 2.568
2015 22.4 6.775 2.602
2016 23.5 7.492 2.608
2017 24 8.127 2.635
2018 24.4 7.468 2.657
2019 24.8 6.976 2.656
2020 25.1 7.115 2.605
2021 22

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