明华 曾;波 汪;Xin Yi Wang;Wei Xiong Zhang;小明 陈;松 高
Sun Yat-Sen University;Guangxi Normal University;Peking University
发表时间:2006-9-4
期 刊:Inorganic Chemistry
语 言:English
U R L: http://www.scopus.com/inward/record.url?scp=33748776541&partnerID=8YFLogxK
The isostructural, chiral molecular magnetic materials with the formula [MxM′(ca)2(1,4-dimb)]n [H2ca = D-(+)-camphoric acid, 1,4-dimb = 1,4-di-(1-imidazolyl-methyl)-benzene, M = NiII, M′ = CoII, 0 ≤ x ≤ 2] consist of ca-bridged (4,4) layers with [M2(O2CR)4] as secondary building units that are pillared by the 1,4-dimb ligands into a unique 3D framework. The high-spin octahedral symmetry and the proportions of the mixed-metal ions were characterized by UV-vis spectroscopy. The compounds exhibit the onset of antiferromagnetic ordering at 7.5-23 K, as well as weak ferromagnetism, spin-flop, and glassy behavior that result from the randomness of the mixed-metal pairs, magnetic anisotropy of the metallic cations, and antisymmetric exchange. The composites should be regarded as molecular alloys of the pure Ni(II) and Co(II) compounds. The magnetic behavior of the solid solutions shows unambiguously that the organic bridges, bond angles, and bond distances greatly influence the effective interactions and bring about cooperative magnetic behavior in the chiral 3D frameworks.
Scopus度量
年份 | CiteScore | SJR | SNIP |
---|---|---|---|
1996 | |||
1997 | |||
1998 | |||
1999 | 1.68 | 1.361 | |
2000 | 1.688 | 1.366 | |
2001 | 1.774 | 1.427 | |
2002 | 1.631 | 1.339 | |
2003 | 1.548 | 1.454 | |
2004 | 1.693 | 1.353 | |
2005 | 2.049 | 1.429 | |
2006 | 1.862 | 1.52 | |
2007 | 2.165 | 1.567 | |
2008 | 2.097 | 1.485 | |
2009 | 2.014 | 1.528 | |
2010 | 2.006 | 1.31 | |
2011 | 7.6 | 1.921 | 1.317 |
2012 | 7.8 | 2.094 | 1.331 |
2013 | 7.9 | 1.821 | 1.366 |
2014 | 8.2 | 1.867 | 1.296 |
2015 | 8.5 | 1.782 | 1.23 |
2016 | 8.4 | 1.804 | 1.204 |
2017 | 8.1 | 1.892 | 1.121 |
2018 | 7.8 | 1.501 | 1.099 |
2019 | 7.9 | 1.349 | 1.164 |
2020 | 8 | 1.348 | 1.113 |
2021 | 7.3 |
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